If you can watch only one, watch the series Chicano! (available online)
Other documentaries worth watching:
http://www.amazon.com/Viva-La-Causa-Movement-Justice/dp/B001VA4DH4/ref=pd_cp_mov_2
http://www.chavezfoundation.org/zencart/index.php?main_page=product_info&products_id=24
http://www.newday.com/films/Los_Trabajadores.html
Fictionalized accounts: